Synthesis and complex formation of substituted aminoglyoximes of unsymmetrical vic-dioximes

Three new substituted aminoglyoximes, p-chloro-anilinoglyoxime (P-CAGH2), o-chloroanilinoglyoxime (0-CAGH2), m-chloroanilinoglyoxime (m-CAGH2) have been synthesized from anti -chloroqlvoxime (CPGH2) and the corresponding substituted amines. The Ni(II) and Cu(II) complexes of these ligands are square-planer while the Co(II) complexes are octahedral with water molecules as axial ligands. 1H-NMR, mass, IR spectra and elemental analyses data of the new compounds are given. © 1994, Taylor & Francis Group, LLC. All rights reserved.