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Synthesis and dichromate anion extraction ability of p-tert-butylcalix[4]arene diamide derivatives with different binding sites

Tetrahedron · Haziran 2007

Özet
The article describes the synthesis and evaluation of the dichromate anion (Cr2O72-/HCr2O7-) extraction properties of p-tert-butylcalix[4]arene diamide derivatives (5-7) containing different binding sites. Among these compounds, 6 and 7 have been synthesized via aminolysis in a toluene-methanol solvent system with 3-aminomethylpyridine and 3,6-dioxa-1,8-diamino octane, respectively. On the other hand, compound 5 has been synthesized via an acid chloride method due to its inefficiency under aminolysis. The extraction properties of these diamides toward dichromate anions are studied by liquid-liquid extraction. The results show that p-tert-butylcalix[4]arene diamide derivative 7 exhibited a much higher affinity toward dichromate anions than that of 6 due to its special structure, while 5 was an ineffective ligand for these anions. © 2007 Elsevier Ltd. All rights reserved.
47 atıf Haziran 2007 DOI
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YÖKSİS Kayıtları
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Makale Bilgileri

Toplam Atıf 47 atıf · Scopus
ISSN00404020
Yayın TarihiHaziran 2007
Cilt / Sayfa63 · 5000-5005

Kurumlar

Selçuk Üniversitesi
Selçuklu Turkey

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Bu makaleye, sistemimizdeki Scopus veritabanında bulunan 0 makale atıf yapmıştır. Scopus genel atıf sayısı: 47.

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Scimago Dergi (ISSN Eşleşmesi)
Tetrahedron
Q3
SJR Skoru0,360
H-Index245
YayıncıElsevier Ltd
ÜlkeUnited Kingdom
Biochemistry (Q3)
Drug Discovery (Q3)
Organic Chemistry (Q3)
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47
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