This article describes and explains the tribological tests and methods for the evaluation of the performance of the brake friction materials. It starts by discussing the particularities of these materials and the variation of characterization tests, which can experimentally simulate many aspects of brake situation but with a large field of tribo-test, from standard to specific protocol. Examples of preparation, procedures, instrumentation, and analysis results for the tribological aspect testing ranging from the scale of vehicle braking performance (by methods including inertia dynamometers, Krauss testing, friction assessment screening test, and Chase testing) to simplified test using reduced-scale prototypes for small-sample friction, are explained. A particular attention is attributed to the discussion of the viability of the friction coefficient report in relation to the material properties and brake compound performance. At the end of this article, the guarantee of the performance output or ranking evaluated by such experimental methods is discussed.