In this study a thin film composite (TFC) membrane was fabricated using initiated chemical vapor deposition (iCVD) of poly(glycidyl methacrylate-diethylamino ethyl methacrylate) thin films on porous fabric membrane supports. iCVD allowed very high deposition rates (50 nm min-1) at low substrate temperatures. SEM analysis confirmed that iCVD forms a defect-free blanket type coating over the support surface. The resultant TFC membrane was used for the selectively facilitated transport of Cr(VI) with a maximum transport amount of 81.25% in aqueous medium. The transport efficiency of the TFC membrane was reproducible and it could be efficiently used in the long-term separation processes.