Kurumun Atıf Alan Makalesi
Atıf Alan Yayın
On-site and low-cost detection of cyanide by simple colorimetric and fluorogenic sensors: Smartphone and test strip applications
Scopus
Toplam 131 atıf DOI
Cyanide is potentially hazardous and quickly acting chemical used in many fields of industry. Therefore, detection of cyanide is of main health concern due to its serious impacts on living organisms. In this context, we have developed rapid, low-cost and on-site sensory two molecules for the colorimetric and fluorogenic sensing of cyanide ion in aqueous samples and food samples. The prepared probes undergo distinct visual color change and exhibits selective fluorogenic turn-on or turn-off response towards cyanide. Competing anions have little or negligible effect on the detection of cyanide. The limit of detection for cyanide ion was calculated as low as 0.45 μM. Free receptors could be successfully regenerated by treating them with Ag+ ion. Moreover, a new visual colorimetric strip based on paper was fabricated with the pale yellow-to-pink color change signal. The fabricated test strips also demonstrated excellent selectivity towards cyanide ion without interfering possible fluoride and acetate ions. The smartphone-based technique which could directly read out the color value using a smartphone revealed an excellent potential for the cyanide detection without additional device.
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Atıf Yapan Yayın
Visual and quantitative detection of CN− ion in aqueous media by an HBT-Br and thiazolium conjugated fluorometric and colorimetric probe: Real samples and useful applications
Scopus
Havuzumuzda 51 atıf almış
Cyanide released from mostly industrial production is a highly toxic chemical. Its heavy industrial use and transportation increase the danger of human exposure. Since it can often lead to rapid death, selective, sensitive and on-site and rapid monitoring techniques for the detection of cyanide are essential. Therefore, we report an efficient cyanide probe based on thiazolium conjugated HBT-Br derivative. It has striking color change toward cyanide blue to yellow under daylight or colorless to cyan under UV-light. Interaction modes of the probe are based on ESIPT and ICT processes. It is selectively able to react free aqueous cyanide with detection limit of 1.79 μM, lower than physiologically lethal blood levels, >20 μM. Smartphone assisted and test kit applications are able to detect cyanide, qualitatively. Moreover, real samples such as tap or lake water and apricot seeds including cyanide are successfully determined through the present probe. Therefore, the designed probe displays excellent practical potential toward cyanide.
Atıf Yapan Makale Bilgileri
Kurumlar (2)
Giresun Üniversitesi
Giresun, Turkey
Selçuk Üniversitesi
Selçuklu, Turkey