Kurumun Atıf Alan Makalesi
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Removal efficiency of a calix[4]arene-based polymer for water-soluble carcinogenic direct azo dyes and aromatic amines
Scopus
Toplam 131 atıf DOI
A Mannich base derivative of 5,11,17,23-tetrakis-[(1,4-dioxa-8-azaspiro-[4.5]decanyl)methyl]-25,26,27,28-tetrahydroxy calix[4]arene 3 was synthesized by the treatment of calix[4]arene with a cyclic secondary amine (1,4-dioxa-8-azaspiro-[4.5]decane) and formaldehyde. The compound 3 was treated with dibromoxylene to obtain a calix[4]arene-based copolymer 4. In batch sorption experiments of selected carcinogenic azo dyes and aromatic amines, the compounds 3 and 4 were found to be a better sorbent for azo dyes than for the aromatic amines. It was observed that the percentage of azo dye removal was 95-99% for compound 3 and 83-97% for 4 when the pH of the dye solution was in the range of 2.0-8.0. The sorption of azo dyes and aromatic amines by calix[4]arenes-based compounds indicates that amino groups play the major role for the formation of hydrogen bonds and electrostatic interactions. © 2008 Elsevier B.V. All rights reserved.
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Atıf Yapan Yayın
Removal of direct azo dyes and aromatic amines from aqueous solutions using two β-cyclodextrin-based polymers
Scopus
Havuzumuzda 110 atıf almış
Two β-cyclodextrin (β-CD)-based polymers were synthesized using 4,4′-methylene-bis-phenyldiisocyanate (MDI) or hexamethylenediisocyanate (HMDI) as a cross linking agent in dimethylformamide and used as sorbents for the removal of azo dyes (Evans Blue and Chicago Sky Blue), as well as aromatic amines (benzidine, p-chloroaniline and α-naphthalamine) from aqueous solutions. The sorption experiments were carried out by using batch-wise procedure involving the determination of pH effect, sorbate concentration and contact time. Moreover, from the equation isotherms such as Langmuir and Freundlich were successfully applied to model the experimental data. From the results polymer 2 was found to be a better sorbent for both azo dyes and the aromatic amines as compared to polymer 1 as proved by Langmuir isotherm model. The proposed sorption mechanism involved several kinds of interactions: physical adsorption, hydrogen bonding and formation of an inclusion complex due to the β-CD molecules through host-guest interactions. © 2009 Elsevier B.V. All rights reserved.
Atıf Yapan Makale Bilgileri
Kurumlar (2)
Selçuk Üniversitesi
Selçuklu, Turkey
University of Sindh
Jamshoro, Pakistan