Kurumun Atıf Alan Makalesi
Atıf Alan Yayın
Synthesis of β-cyclodextrin and starch based polymers for sorption of azo dyes from aqueous solutions
Scopus
Toplam 156 atıf DOI
Three β-cyclodextrin (polymers 1-3) and a starch-based (polymer 4) polymers were synthesized using hexamethylene diisocyanate (HMDI) as a cross-linking agent in dry dimethylformamide and used as a sorbent for the removal of some selected azo dyes from aqueous solutions. The cross-linked polymers were characterized by Fourier transform infrared spectroscopy, thermogravimetric and differential scanning calorimetric analysis. Results of sorption showed that cyclodextrin and starch based polymers can be effectively used as a sorbent for the removal of anionic azo dyes. The Influence of the amide groups and the chemical structure of azo dyes are also studied. Results of sorption experiments showed that these adsorbent exhibited high sorption capacities toward Direct Violent 51 (80% for polymer 1, 69% for polymer 2, 70% for polymer 3 and 78% for polymer 4). The sorption capacity of dyes on the polymers was dependent on the presence of sulfonate groups of the anionic dyes. In order to explain the results an adsorption mechanism mainly physical adsorption and interactions such as hydrogen bonding, ion-exchange due to the nature of the polymer network and the formation of an inclusion complex due to the β-CD molecules through host-guest interaction is proposed. © 2007 Elsevier Ltd. All rights reserved.
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Atıf Yapan Yayın
Removal of direct azo dyes and aromatic amines from aqueous solutions using two β-cyclodextrin-based polymers
Scopus
Havuzumuzda 110 atıf almış
Two β-cyclodextrin (β-CD)-based polymers were synthesized using 4,4′-methylene-bis-phenyldiisocyanate (MDI) or hexamethylenediisocyanate (HMDI) as a cross linking agent in dimethylformamide and used as sorbents for the removal of azo dyes (Evans Blue and Chicago Sky Blue), as well as aromatic amines (benzidine, p-chloroaniline and α-naphthalamine) from aqueous solutions. The sorption experiments were carried out by using batch-wise procedure involving the determination of pH effect, sorbate concentration and contact time. Moreover, from the equation isotherms such as Langmuir and Freundlich were successfully applied to model the experimental data. From the results polymer 2 was found to be a better sorbent for both azo dyes and the aromatic amines as compared to polymer 1 as proved by Langmuir isotherm model. The proposed sorption mechanism involved several kinds of interactions: physical adsorption, hydrogen bonding and formation of an inclusion complex due to the β-CD molecules through host-guest interactions. © 2009 Elsevier B.V. All rights reserved.
Atıf Yapan Makale Bilgileri
Kurumlar (2)
Selçuk Üniversitesi
Selçuklu, Turkey
University of Sindh
Jamshoro, Pakistan