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A new electrochemical sensor based on Fe3O4 functionalized graphene oxide-gold nanoparticle composite film for simultaneous determination of catechol and hydroquinone
Electrochimica Acta Cilt 186 ss. 302-313
Scopus Toplam 238 atıf DOI
Catechol (1,2-dihydroxybenzene) and hydroquinone (1,4-dihydroxybenzene) are two isomers of phenolic compounds which often coexist and interfere with each other during their identification in environmental samples. This study presents simultaneous determination of catechol (CC) and hydroquinone (HQ) using a new electrochemical sensor based on Fe3O4 functionalized graphene oxide-gold nanoparticle composite (AuNPs/Fe3O4-APTES-GO). CV results show well-defined oxidation peaks with anodic peaks at 0.15 V for CC and 0.05 V for HQ, and the peak-to-peak separation for CC and HQ is about 100 mV. Under the optimized conditions, the current response of AuNPs/Fe3O4-APTES-GO/GCE is linear for CC and HQ in the range of 2-145 μM and 3-137 μM, respectively. The detection limits for CC and HQ were found to be 0.8 μM and 1.1 μM, respectively. The fabricated sensor was successfully applied for the determination of CC and HQ in tap water sample with satisfactory recovery.
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Electrochemical detection of bisphenol A in water samples through a ternary nanocomposite-based laboratory-made sensing platform
Journal of Environmental Chemical Engineering Cilt 13
Scopus Havuzumuzda Open Access 12 atıf almış
Bisphenol A (BPA), a plastic additive widely used in many polymeric products, disrupts the endocrine system by interfering with hormonal and homeostatic functions. Due to concerns about the health effects of BPA, it is crucial to detect BPA in order to control this potential risk in a timely manner. To this end, we have developed a laboratory-made, disposable sensing platform to detect BPA rapidly and easily using a ternary nanocomposite comprising tungsten disulfide (WS2), magnetite (Fe3O4), and reduced graphene oxide (rGO) to enhance the electroactive properties of the sensor. Comprehensive structural and electrochemical characterizations were conducted to evaluate the performance of each nanomaterial constituting the ternary composite. The sensor demonstrated a good linear response ranging from 0.05μM to 50μM, with a limit of detection (LOD) of 0.03μM. Additionally, the sensor exhibited acceptable stability, strong anti-interference ability, good reproducibility, and repeatability. The proposed sensor was also utilized to detect BPA in tap and spring water samples with a satisfactory recovery rates from 103.50% to 105.25%. These findings suggest the sensor's potential as a reliable platform for monitoring BPA. From all these results, it can be concluded that the ternary composite of WS2, Fe3O4, and rGO offers significant insights for the electrochemical monitoring of BPA.
Atıf Yapan Makale Bilgileri
Kurumlar (3)
Karamanoğlu Mehmetbey Üniversitesi Karaman, Turkey
Recep Tayyip Erdogan University Rize, Turkey
Selçuk Üniversitesi Selçuklu, Turkey